Adfa, Morina and Hattori, Yosuke and Yoshimura, Tsuyoshi and Koketsu, Mamoru (2012) Antitermite activity of 7-alkoxycoumarins and related analogs against Coptotermes formos anus Shiraki. Antitermite activity of 7-alkoxycoumarins and related analogs against Coptotermes formos anus Shiraki, 74. pp. 129-135. ISSN 0964-8305
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Abstract
Twenty-three 7-alkoxycoumarins an d related analog s were synth esized from 7-hydroxycoum arin by treatment wit h vari ous alkyl/aryl/acyl halides and potassium carbonate in DMF. Their antifee dant and termiticidal activities agai nst Coptotermes formosanus Shiraki were examine d. Am ong t h e 2 3 c o mpounds and control, 7-cyclohexyloxycoum arin ( 2k ), exhib ited the highest termiticidal activity in no-choi ce test, followed by 7-(4-nitrophenoxy)c ouma rin ( 2q ), and 7- (2-butynyloxy)cou marin ( 2u )at 5 m mo l/disc. On the other ha nd, all of 7-alkoxycoumarins showed antifee dant activity except 7-hexadecyloxycou marin ( 2i ) and 7-o ctadecyloxycou marin ( 2j ), while 7-eth oxycoum arin ( 2b ) demon strated the highes t antifeeda nt activity. The results sug gested that a presence of cyclohexyloxy and aryloxy groups at C-7 positio n o f couma rin skeleton wa s found to be importa nt for the termiticidal and antifee dant activities. Arylalkoxy groups having meth ox y groups at be nzene ri ng, alke noxy, and alkyn ox y groups led to analogs with good termiticidal activity, w h ile the incorpo ration of alkoxy groups with lon ger alkyl chai ns tended to reduce both the termiticidal and antifee dant activities.
Item Type: | Article |
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Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Math & Natural Science > Department of Chemistry Science |
Depositing User: | 001 Bambang Gonggo Murcitro |
Date Deposited: | 04 Apr 2019 08:19 |
Last Modified: | 04 Apr 2019 08:19 |
URI: | http://repository.unib.ac.id/id/eprint/15370 |
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